Objective
This article delineates the list of impurity species currently available in MSE and MSE-SRK, which are typical of CO2-rich streams in CCTUS applications.
Disclaimer: The following lists pertain to OLI software Version 12.
MSE (V12)
Impurities that may cause acid (sulfuric or nitric) formation and corrosion or elemental sulfur dropout |
• H2O • H2S • O2 • NOx (N2O, NO, N2O3, NO2, N2O5) • SOx (SO2, SO3) |
Impurities that do not cause acid dropout, but alter the phase behavior |
• Alcohols (methanol, monoethylene glycol, diethylene glycol, triethylene glycol) • Hydrocarbons (CH4, C2H6) • Aldehydes (formaldehyde, acetaldehyde) • COS • N2 |
Potential inhibitors |
• Amines (MEA, DEA, DMEA, DMIPA, MDEA, piperazine, DGA, alkyl amines, oxygenated amines) • NH3 (also a potential solid former, i.e., NH2CO2NH4) |
Other impurities, such as heavy metal or non-condensable gases, that cause other transport challenges |
• Hg |
Solids |
• Elemental sulfur
|
MSE-SRK (V12)
Impurities that may cause acid (sulfuric or nitric) formation and corrosion or elemental sulfur dropout |
• H2O • H2S |
Impurities that do not cause acid dropout, but alter the phase behavior |
• Alcohols (methanol) • Some Hydrocarbons • N2 |
Other impurities, such as heavy metal or non-condensable gases, that cause other transport challenges |
• Hg |
Upcoming Software Release
The following impurities will be available in the next MSE release:
Impurities that do not cause acid dropout, but alter the phase behavior |
• Light hydrocarbons (C1-C6) interactions with sulfuric acid species • Ar |
Other impurities such as heavy metal or non-condensable gases that cause other transport challenges |
• CO • H2
|
Solids |
• Solid H2SO4 and HNO3 • Salts associated with acid dropout in the presence of other impurities (e.g., ammonium sulfates) |
The following impurities will be available in the next MSE-SRK release:
Impurities that may cause acid (sulfuric or nitric) formation and corrosion or elemental sulfur dropout |
• O2 |
Impurities that do not cause acid dropout, but alter the phase behavior |
• Ar • N2
|
Other impurities such as heavy metal or non-condensable gases that cause other transport challenges |
• CO • H2 |